PPS (Polyphenylene Sulphide) — EngMats Datasheet
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Engineering Materials Database
Engineering Plastics
PPS (Polyphenylene Sulphide)
High-Performance Polymer
PPS — semi-crystalline high-performance polymer. 220 C service temperature, exceptional chemical resistance. For automotive fuel system components, chemical pump parts and electrical connectors.
Standards
Standard Body Designation Country
ISO PPS (ISO 10112) International
EN EN ISO 10112 European Union
ASTM D5313 (PPS) USA
Trade Names Ryton (Solvay) / Fortron (Celanese) / Torelina (Toray) / Kepstan (Arkema) Global
Key Grades PPS unfilled / PPS GF40 (40% glass fibre) / PPS CF30 (carbon fibre) / PPS GF+Min Global
UL 94 V-0 (inherent flame retardance at 0.8 mm) USA
JIS PPS (JIS K 7209) Japan
GOST PPS (adopted) Russia / CIS
FDA 21 CFR 177.2490 (food contact — unfilled natural grades) USA
JUS PL-PPS Yugoslavia / Serbia
RoHS Compliant EU
Supply Forms Injection moulding compound (primary) + rod and sheet (stock shapes, less common) Global
Composition (wt.%)
Element Symbol Min % Max % Typical %
Carbon (phenylene sulphide backbone) C — — 63.700
Hydrogen H — — 3.180
Sulphur (thioether linkage) S — — 28.900
Oxygen (trace) O — — —
Water absorption (any condition) H2O — 0.030 —
Physical
Density
1.36
g/cm³
Melting Range
270 – 285
°C
Thermal Conductivity
0.3
W/mK
Thermal Expansion
49
×10⁻⁶/K
Young's Modulus
3.8
GPa
Magnetic
No
Machinability
Rating 100.0% (B1112=100%)
Turning HSS 350.0 m/min
Turning Carbide 1200.0 m/min
Surface Finish Ra 0.4-1.6 um
Coolant Dry cutting or light MQL; no flood water need…
Mechanical
Condition Rm (MPa)Re (MPa)A (%) HBHRCKV (J)E (GPa)
PPS Unfilled (standard) (STD) 65 – 85 60 – 80 2 – 4 — — — 3.8
PPS GF40 (40% glass fibre) (GF40) 130 – 170 115 – 155 1 – 2 — — — 14
PPS CF30 (30% carbon fibre) (CF30) 150 – 190 140 – 175 ≥1 — — — 17
Heat Treatment
Process Temperature Medium Duration Hardness After
Annealing (crystallisation) 200 – 220°C Circulating air oven 1-4 h Increased crystallinit
Drying (optional but recommended) 120 – 135°C Circulating air oven 3-4 h Moisture <0.01%
Applications
Automotive: Fuel system components (fuel pumps, injector housings, filter bodies), transmission control modules and under-hood electrical connectors operating at elevated temperatures.
Chemical Pumps: Pump impellers, casings and valve bodies for aggressive chemical service — withstands HCl, H2SO4 and many solvents.
Electronics / PCB: SMT solder-tolerant connectors, relay bodies and PCB-mount components requiring reflow soldering compatibility (260 C Tg compatible).
Aerospace: Electrical connector inserts, clamp components and fluid handling parts in aircraft wet bays.
Notes
Chemical Resistance: Outstanding — one of the best of all thermoplastics. Resists virtually all organic solvents, strong acids (including HCl, H2SO4), bases and fuels below 200 C. No known solvent below 200 C. Only fluorinated polymers (PTFE, PVDF) have broader resistance.
vs PEEK: PPS: better chemical resistance at lower temperatures, significantly lower cost. PEEK: better mechanical properties, higher service temperature (250 C vs 220 C PPS). For most chemical service below 180 C: PPS is the cost-effective choice.
Processing Brittleness: Unfilled PPS can be brittle — design with generous radii. GF40 is standard injection moulding grade for most structural applications.