PTFE (Polytetrafluoroethylene)

PTFE β€” lowest friction coefficient of any solid material. Excellent chemical resistance. For seals, bearings, valve seats and chemical equipment.

Engineering Plastics Fluoropolymer ASTM D1457PTFE (standard) ISOISO 13000 (PTFE) ENEN ISO 13000 Trade NamesTeflon PTFE (Chemours/DuPont) / Fluon PTFE (AGC) / Hostaflon TF (Hoechst) +6
Download PDF Engineering Plastics
Description

PTFE (Polytetrafluoroethylene) per ISO 12086 is a semi-crystalline fluoropolymer with unique properties: (1) coefficient of friction 0.04-0.10 β€” the lowest of any solid material, (2) continuous service temperature -200 to +260 C, (3) resistance to virtually all chemicals including fumic acids, halogens and oxidising media, (4) excellent electrical insulation. Non-meltable by conventional moulding β€” processed by sintering and compression moulding. Reinforced grades (GF/carbon/MoS2/bronze) improve wear resistance.

Key Properties β€” PTFE virgin (compression moulded)
Rm (Tensile Strength)
20 – 30
MPa
Re / Rp0.2 (Yield)
14 – 24
MPa
Aβ‚… (Elongation)
β‰₯ 200.0
%
E (Young's Modulus)
1
GPa
Density
2.16
g/cmΒ³
Main Designations (10)
Standard BodyDesignationCountry / RegionNote
ASTM D1457 PTFE (standard) USA
ISO ISO 13000 (PTFE) International
EN EN ISO 13000 EU
Trade Names Teflon PTFE (Chemours/DuPont) / Fluon PTFE (AGC) / Hostaflon TF (Hoechst) Global
Key Grades PTFE virgin / PTFE GF25 / PTFE CF25 / PTFE+graphite / PTFE+MoS2 / Expanded PTFE (ePTFE) Global
UL 94 V-0 (inherent) USA
FDA 21 CFR 177.1550 (food contact) USA
NSF NSF/ANSI 51 (food equipment) USA
JUS PL-PTFE Yugoslavia Politetrafluoroetilen; JUS G.S5.080
Processing Compression moulding or RAM extrusion ONLY β€” cannot be injection moulded Global
Standards (10)
#Standard BodyDesignationCountry / RegionNote
1 ASTM D1457 PTFE (standard) USA β€”
2 ISO ISO 13000 (PTFE) International β€”
3 EN EN ISO 13000 EU β€”
4 Trade Names Teflon PTFE (Chemours/DuPont) / Fluon PTFE (AGC) / Hostaflon TF (Hoechst) Global β€”
5 Key Grades PTFE virgin / PTFE GF25 / PTFE CF25 / PTFE+graphite / PTFE+MoS2 / Expanded PTFE (ePTFE) Global β€”
6 UL 94 V-0 (inherent) USA β€”
7 FDA 21 CFR 177.1550 (food contact) USA β€”
8 NSF NSF/ANSI 51 (food equipment) USA β€”
9 JUS PL-PTFE Yugoslavia Politetrafluoroetilen; JUS G.S5.080
10 Processing Compression moulding or RAM extrusion ONLY β€” cannot be injection moulded Global β€”
All values in wt.%
F
Fluorine (all C-F bonds)
~76.0000
C
Carbon
~24.0000
H2O
Water absorption (any condition)
≀ 0.0100
ElementSymbolMin %Max %Typical %
Fluorine (all C-F bonds) F β€” β€” 76.0000
Carbon C β€” β€” 24.0000
Water absorption (any condition) H2O β€” 0.0100 β€”
Mechanical Properties
ConditionCode Rm min
MPa
Rm max
MPa
Re min
MPa
Re max
MPa
Aβ‚… min
%
Z
%
KV
J
HB minHB max HRC minHRC max E
GPa
PTFE virgin (compression moulded) STD 20 30 14 24 200.0 β€” β€” β€” β€” β€” β€” 0.5
PTFE GF25 (glass-filled) GF25 25 40 18 32 150.0 β€” β€” β€” β€” β€” β€” 1.0
PTFE CF25 (carbon-filled) CF25 22 35 16 28 100.0 β€” β€” β€” β€” β€” β€” 0.8
Physical Properties
Density
2.160
g/cmΒ³
Melting Point
327–342
Β°C
Young's Modulus
0.5
GPa
Poisson's Ratio
0.460
β€”
Thermal Conductivity
0.3
W/mΒ·K
Thermal Expansion
135.00
Γ—10⁻⁢ /K
Specific Heat
1,050
J/kgΒ·K
Magnetic
No
 
Heat Treatment
No heat treatment β€” processing only
Medium:Sintering at 370-390 C during moulding
Duration:N/A
Cooling:N/A
Hardness After:N/A
PTFE is processed by cold pressing then sintering β€” not injection moulding.
Service Temperature Limits
Temperature:-200Β°C – 260Β°C
Medium:Continuous
Duration:Indefinite
Cooling:N/A
Hardness After:Full properties
-200 C cryogenic to +260 C continuous. Short-term to 300 C. Above 380 C: toxic PFIB gas released.
Machinability
Machinability Rating
relative to AISI B1112 = 100%
400.0%
Excellent
Feed Rate (Turning)
0.700
mm/rev
CoolantDry; compressed air chip removal; LN2 cryogenic machining gives best results
Chip FormationExtremely long waxy stringy gummy chips β€” worst of all polymers; cryogenic machining standard
Tool MaterialPCD or very sharp uncoated carbide; cryogenic machining strongly recommended for production
Surface FinishRa 0.8-6.3 um (poor) β€” PTFE is elastically soft; better with cryogenic
Worst machinability of common polymers β€” extreme chip control problems. Cryogenic machining (LN2) is essential for production. Standard production: compression moulding, machining oversize then skive-cutting for tube/sheet stock.
Applications
Seals
O-ring substitutes, backup rings, stem packing and valve seats in chemical service.
Gaskets
Flange gaskets for chemical plant, pharmaceutical and food processing.
Bearings
Self-lubricating plain bearings, slide pads and guide liners (PTFE+GF25 or +bronze).
Coatings
Non-stick cookware coating, industrial roll coatings, anti-stick equipment lining.
Chemical Lining
Tank and vessel lining, pipe lining and chemical reactor lining.
Technical Notes
πŸ’§
Chemical Resistance
The broadest chemical resistance of any commercial material. Resists: all organic solvents, all common acids (including HF, aqua regia, fuming HNO3), all bases, oxidising agents and reducing agents. NOT resistant to: elemental fluorine, alkali metals (Na, K) and certain reactive fluorinating agents.
βœ…
PTFE vs PFA
PTFE: wider chemical resistance, lowest friction, compression-mouldable only, very low creep resistance. PFA: nearly same chemical resistance, injection-mouldable, 3x better creep resistance, slightly lower temperature limit (260 C same). Use PFA when melt-processing is needed; PTFE for maximum chemical resistance or gaskets/seals.
⚠️
Creep (Cold Flow)
PTFE has extremely poor creep resistance β€” will deform under sustained load even at room temperature. Unfilled PTFE gaskets require regular re-torquing. PTFE+GF25 dramatically improves creep resistance. Never use unfilled PTFE as a load-bearing structural material.