PET (Polyethylene Terephthalate)

PET β€” transparent engineering thermoplastic with good barrier properties. For beverage bottles, food packaging, film, fibres and light engineering parts.

Engineering Plastics Engineering Thermoplastic ISOPET (ISO 7792-1) ENEN ISO 7792 ASTMD4397 / D5927 (PET bottle grade) Trade Names PETArnite (DSM) / Rynite (DuPont) / Hostaphan film (Mitsubishi) +9
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Description

PET (Polyethylene Terephthalate) per ISO 7792 is a semi-crystalline polyester widely used as a packaging material (PET bottles) and as an engineering thermoplastic. It offers good tensile strength, excellent dimensional stability, low water absorption and good chemical resistance. As an engineering plastic, PETG (glycol-modified PET) and crystalline CPET are used for food trays, medical packaging and precision machined parts.

Key Properties β€” Standard PETG (amorphous)
Rm (Tensile Strength)
45 – 60
MPa
Re / Rp0.2 (Yield)
45 – 55
MPa
Aβ‚… (Elongation)
β‰₯ 50.0
%
E (Young's Modulus)
2
GPa
Density
1.38
g/cmΒ³
Main Designations (13)
Standard BodyDesignationCountry / RegionNote
ISO PET (ISO 7792-1) International
EN EN ISO 7792 European Union
ASTM D4397 / D5927 (PET bottle grade) USA
Trade Names PET Arnite (DSM) / Rynite (DuPont) / Hostaphan film (Mitsubishi) Global
Trade Names PETG Eastman Tritan / Vivak (Sheffield Plastics) / Spectar (Eastman) Global Glycol-modified PET β€” better clarity, no stress-whitening
UL 94 HB (standard PET) USA
JIS PET (JIS K 7367) Japan
GOST Polietilentereftalat (PET) Russia / CIS
FDA 21 CFR 177.1630 (food contact) USA FDA approved for food and beverage contact
JUS PL-PET Yugoslavia / Serbia Polyethylene terephthalate engineering plastic
RoHS Compliant EU
Supply Forms Rod, sheet (extruded) + preforms (blow moulding) + film (Mylar/Melinex) + injection moulding compound Global
Recycling code 1 β€” PET (most recycled plastic globally) Global
Standards (13)
#Standard BodyDesignationCountry / RegionNote
1 ISO PET (ISO 7792-1) International β€”
2 EN EN ISO 7792 European Union β€”
3 ASTM D4397 / D5927 (PET bottle grade) USA β€”
4 Trade Names PET Arnite (DSM) / Rynite (DuPont) / Hostaphan film (Mitsubishi) Global β€”
5 Trade Names PETG Eastman Tritan / Vivak (Sheffield Plastics) / Spectar (Eastman) Global Glycol-modified PET β€” better clarity, no stress-whitening
6 UL 94 HB (standard PET) USA β€”
7 JIS PET (JIS K 7367) Japan β€”
8 GOST Polietilentereftalat (PET) Russia / CIS β€”
9 FDA 21 CFR 177.1630 (food contact) USA FDA approved for food and beverage contact
10 JUS PL-PET Yugoslavia / Serbia Polyethylene terephthalate engineering plastic
11 RoHS Compliant EU β€”
12 Supply Forms Rod, sheet (extruded) + preforms (blow moulding) + film (Mylar/Melinex) + injection moulding compound Global β€”
13 Recycling code 1 β€” PET (most recycled plastic globally) Global β€”
All values in wt.%
C
Carbon (terephthalate ester repeat unit)
~62.5000
H
Hydrogen
~4.1600
O
Oxygen (ester groups)
~33.3000
H2O
Water absorption (equilibrium 50% RH)
≀ 0.4000
ElementSymbolMin %Max %Typical %
Carbon (terephthalate ester repeat unit) C β€” β€” 62.5000
Hydrogen H β€” β€” 4.1600
Oxygen (ester groups) O β€” β€” 33.3000
Water absorption (equilibrium 50% RH) H2O β€” 0.4000 β€”
Mechanical Properties
ConditionCode Rm min
MPa
Rm max
MPa
Re min
MPa
Re max
MPa
Aβ‚… min
%
Z
%
KV
J
HB minHB max HRC minHRC max E
GPa
Standard PETG (amorphous) PETG 45 60 45 55 50.0 β€” β€” β€” β€” β€” β€” 2.2
Crystalline PET (CPET) CPET 55 75 50 65 20.0 β€” β€” β€” β€” β€” β€” 2.7
PET GF30 (glass-filled) GF30 110 140 95 120 3.0 β€” β€” β€” β€” β€” β€” 8.0
Physical Properties
Density
1.380
g/cmΒ³
Melting Point
245–260
Β°C
Young's Modulus
2.7
GPa
Poisson's Ratio
0.380
β€”
Thermal Conductivity
0.3
W/mΒ·K
Thermal Expansion
65.00
Γ—10⁻⁢ /K
Specific Heat
1,350
J/kgΒ·K
Magnetic
No
 
Heat Treatment
Drying (mandatory)
Temperature:70Β°C – 80Β°C
Medium:Circulating air oven
Duration:4-6 h
Cooling:Sealed bag
Hardness After:Moisture <0.02%
MANDATORY before processing. PET is extremely hygroscopic and undergoes hydrolytic degradation when processed wet.
Crystallisation (for CPET)
Temperature:120Β°C – 160Β°C
Medium:Oven
Duration:30-60 min
Cooling:Controlled cool
Hardness After:Whitening / opaque
Amorphous PET becomes crystalline (CPET) by heating above glass transition. Improves thermal stability.
Annealing (machined parts)
Temperature:60Β°C – 70Β°C
Medium:Air oven
Duration:1-2 h
Cooling:Slow cool
Hardness After:Stress relief
Recommended for precision PETG machined parts.
Machinability
Machinability Rating
relative to AISI B1112 = 100%
250.0%
Good
Turning Speed (HSS)
450
m/min
Turning Speed (Carbide)
1,800
m/min
Feed Rate (Turning)
0.600
mm/rev
Drilling Speed (HSS)
420
m/min
Milling Speed (Carbide)
1,800
m/min
CoolantCompressed air or dry MQL; no flood water (water can cause surface hazing in amorphous PETG)
Chip FormationGood chip formation; medium-short chips; better than PA
Tool MaterialCarbide K10 or HSS M2; sharp tools; positive rake
Surface FinishRa 0.4-1.6 um
Good machinability. PETG machines cleanly with sharp tools. GF30 is abrasive β€” carbide only.
Applications
Packaging
PET bottles (carbonated beverages, water, juices) β€” single largest application globally.
Film & Fibres
Mylar/Melinex film for capacitors, packaging, solar panels; polyester fibres for clothing and insulation.
Medical Packaging
Trays, blisters, clamshells and medical device packaging (gamma sterilisable).
Engineering Parts
Precision machined parts from PETG rod/sheet where transparency or food contact is required.
3D Printing
PETG filament β€” widely used FDM material combining ease of printing with good mechanical properties.
Technical Notes
βœ…
PET vs PETG
Standard PET is brittle and stress-whitens during machining/forming. PETG (glycol-modified) eliminates stress whitening, has better impact resistance and is much easier to machine/thermoform. For engineering stock shapes, always specify PETG or Tritan.
βœ…
3D Printing
PETG is one of the best FDM materials: easier to print than ABS (no warping, no fumes), better mechanical properties than PLA, excellent layer adhesion. Widely recommended for functional prototypes.
πŸ’§
Chemical Resistance
Good resistance to dilute acids, oils and many solvents. NOT resistant to: strong bases (saponification of ester bonds), acetone, MEK, chlorinated solvents. Excellent barrier to CO2 and O2 (hence use for carbonated beverage bottles).